Experimental investigation on the phase behaviour for gas hydrates in CO2 rich gas mixtures & multiphase system

Kinetics of the Formation and Dissociation of Gas Hydrates from CO2-CH4 Mixtures

Sequestration of carbon dioxide (CO2) in the form of its hydrates in natural methane (CH4) hydrate reservoirs, via CO2/CH4 exchange, is an attractive pathway that also yields valuable CH4 gas as product. In this paper, we describe a macroscale experiment to form CO2 and CH4-CO2 hydrates, under seafloor-mimic conditions, in a vessel fitted with glass windows that provides visualization of hydrat...

Experimental and theoretical investigations on the MMOF selectivity for CO2 vs. N2 in flue gas mixtures.

The adsorption capacity and selectivity of carbon dioxide and nitrogen at 298 K have been evaluated for two series of MMOFs built on metal paddle-wheel building units, including non-interpenetrated Zn(BDC)(TED)(0.5) (1), Zn(BDC-OH)(TED)(0.5) (2), Zn(BDC-NH(2))(TED)(0.5) (3), and interpenetrated Zn(BDC)(BPY)(0.5) (4), Zn(BDC)(DMBPY)(0.5) (5), Zn(NDC)(BPY)(0.5) (6) and Zn(NDC)(DMBPY)(0.5) (7) fra...

Investigation of CO2 and H2O Addition to Natural Gas for Production of Synthesis Gas

General modeling and optimization of syngas production via noncatalytic autothermal partial oxidation of methane are carried out using our developed scientific software which was based on the minimization of total Gibbs energy. In this work, a novel application of the direct search and Newton-Raphson methods was introduced to apply to optimization of a complex chemical reaction. Sensitivity ana...

Phase diagrams of CO2 and CO2 -N2 gas mixtures and their application in compression processes

Phase diagrams of carbon dioxide, nitrogen and their mixtures with different amounts of nitrogen (e.g. 5 mol%, 10 mol% N2) were calculated with high accuracy with the NIST Reference Fluid Thermodynamic and Transport Properties database program REFPROP® for up to 200 bar, as well as density-pressure diagrams. Beside the use of carbon dioxide as a solvent for supercritical fluid extraction, incre...

7 Natural Gas Hydrates